Methylene diphenyl diisocyanate sds Millionate® MR/MT : Millionate MT [Monomeric MDI] Millionate MT is an aromatic diisocyanate having two isocyanate groups of equal reactivity. 0% Keyword:'methylene diisocyanate' Showing 1-1 of 1 result for "methylene diisocyanate" within Products. SDS Number: 4701001 SAP Number: Revision Date: 9/2/2022 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 10-30 GHS07 H332 Propylene glycols 25322-69-4 10-30 No Information No Information Propan-2-oxide, 1,3-dichloro-, phosphate 13674-87-8 5-10 No Information No %PDF-1. ] CDC - NIOSH Pocket Guide to Chemical Hazards - Methylene bisphenyl isocyanate Methylene di-p-phenylene Ceiling 0. Waste treatment 6. WANNATE® 8219 is Modified polyemeric MDI (methylene diphenyl diisocyanate) that is 31. Other adverse effects Do not empty into drains. Baur, X. Diphenylmethane diisocyanate (MDI) is a member of the diisocyanate family associated with polyurethane chemistry. One Reagent Lane Fair Lawn, NJ Methylene diphenyl diisocyanate, 4,4'- (50°C, molten) 101-68-8: Liquid >480 >480 >480 >480 >480 >480 >480 >480 > indicates greater than. Methylene Diphenyl Diisocyanate (CAS 101-68-8) information, including chemical properties, structure, melting point, boiling point, density, formula, molecular weight, uses, prices, suppliers, SDS and more, available at Chemicalbook. 4,4'-Diphenylmethane diisocyanate is not soluble in water. [Note: A liquid above 99°F. Elavin Chemtech Private Limited - Offering Methylene Diphenyl Diisocyanate, For Refrigerator Insulation, Grade: 1342 at ₹ 210/kgs in Ahmedabad, Gujarat. ACGIH Threshold Limit Values Material Type Value Methylene di-p-phenylene TWA 0. The mixture is designated as polymeric MDI 6. 5% 2,4[-isomer; PMDI is the form produced commercially from aniline and formaldehyde using hydrochloric acid as catalyst. Classifications. 1): 1004-1010, 1995. All Photos (2) 4,4′-MDI. - Find MSDS or SDS, a Exposure to temperatures above 120 'F may cause can to rupture. Polymeric MDI is a mixture of Consult your company safety professional or the product SDS for guidance. NIOSH: Occupational Health Guideline for SDS Number: 4700701 SAP Number: Revision Date: 9/2/2022 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 10-30 GHS07 H332 Tris(2-chloro-1-methylethyl) phosphate 13674-84-5 7-13 GHS07 H302-332 We provide Diphenylmethane diisocyanate safety data sheet view and download for free at Echemi. These are distinguished by the locations of the isocyanate groups around the rings. [Note: A concentration of 10 ppm methylene bisphenyl isocyanate is equivalent to about 100 mg/m 3. It exists in three isomers, 2,2'-MDI, 2,4'-MDI, and 4,4'-MDI, however, the 4,4' isomer is most widely used. Show the Safety Data Sheet to the medical personnel. SAFETY DATA SHEET Version 8. Use reasonable care Also find Methylene Diphenyl Diisocyanate price list | ID: 25561282012. : 820797 4,4′-Methylenebis(phenyl isocyanate) (MDI) is an aromatic diisocyanates class of monomer that is widely used in the production of polyurethane plastics, foam insulation, coatings, adhesives, and sealants. One common method for synthesizing Diphenylmethane-4,4’-diisocyanate (MDI) involves the reaction between aniline and formaldehyde, followed by phosgenation. We expect you to follow the precautions Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 100. You must check the information on the packaging and safety data sheet, supplied Note: both ingredients listed in the table are mixtures, which include 4,4’-methylene diphenyl diisocyanate (4,4’-MDI),CAS #101-68-8 . : Call 1-800-222-1222 Outside U. for methylene diphenyl diisocyanate is 0. 005 ppm diisocyanate (CAS 101-68-8) US. ACUTE TOXICITY DATA: Lethal concentration data: Species Reference LC 50 This document addresses the use of methylene diphenyl diisocyanate (MDI) and related compounds (See Appendix 1) in products that may result in consumer and general population exposures, particularly in or around buildings, including homes and schools. Throughout this document, the term MDI is used to address both monomeric MDI and polymeric MDI (pMDI). 1 Product identifiers Product name : 1,1-Diphenylethanol Product Number : 152145 Brand : Aldrich CAS-No. This condensation reaction produces MDA and a complex mixture of polyamines, which are phosgenated to obtain a methylene diphenyl diisocyanate mixture. pure monomeric 4,4'-methylene diphenyl isocyanate (MDI) (CAS number 101–68–8, EC number 615–005–00–9), at temperatures up to 38 °C a whitish-yellow solid which is used in the industrial production of special plastics, varnish and glue components, moulding elastomers and "MDI 2,2'-methylenediphenyl diisocyanate Other names: Methylenediphenyl diisocyanate, mixed isomers; Benzene, 1,1'-methylenebis[isocyanato- Information on this page: 4,4'-diphenylmethane diisocyanate, diphenylmethane diisocyanate, isonate, 4,4'-diisocyanatodiphenylmethane, p,p'-diphenylmethane diisocyanate, bis 4-isocyanatophenyl methane, 4,4'-methylenebis phenyl isocyanate, The Dow Chemical Companyencourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. It is the most produced diisocyanate, accounting for 61. Company Identification: Acros Organics N. The diisocyanates considered are methylene diphenyl diisocyanate (MDI), toluene diisocyanate (TDI), and hexamethylene diisocyanate (HDI), accounting for more than 95% of the market volume in the EU. Methylene diphenyl diisocyanate (MDI) is a white, odorless diisocyanate that may also occur in crystalline form. Tanks: General References Footnote 1. Methylene Diphenyl Diisocyanate Synthesis Methods. 005 ppm Biological limit values ACGIH Biological HUNTSMAN RUBINATE® 1820 is an aromatic isocyanate based on polymeric methylene diphenyl diisocyanate modified with a low level of 2,4'-MDI. The global market for diisocyanates in the year 2000 was 4. Chemical Safety Data Sheet MSDS / SDS 4,4'-Diphenylmethane diisocyanate Revision Date:2025-01-11Revision Number:1 SECTION 1: Identification of the substance/mixture and of the (ITSL) for methylene diphenyl diisocyanate is 0. 1200): EXPOSURE LIMITS Wood Dust/Ligno-cellulosic fiber 1, 2 OSHA PEL – TWA 15. org. 0 mg/m3 (total dust) 3 Diphenylmethane-4,4-diisocyanate is a light yellow colored solid. MDI is the least hazardous of the commonly available isocyanates but is not benign. 341,342,343). 822-06-0. 6 Revision Date 09/06/2024 Print Date 09/06/2024 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1. 15 Revision Date 09/06/2024 Print Date 09/07/2024 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1. Products Building Blocks Explorer Genes Papers Technical Documents Site Content Chromatograms. Supplier. 0 % 4,4' -Methylenediphenyl diisocyanate 101-68-8 > 55. Identification Product identifier DUNAPOL™ AD 3206 V3 Other means of identification SDS number Version 1 Product code 202115 Recommended use Industrial use. Nov 30，2021 Methylene Diphenyl Diisocyanate (monomeric MDI) and polymeric MDI (PMDI) (CASRN 101-68-8, 9016-87-9) 2,4-/2,6-Toluene diisocyanate mixture (TDI) (CASRN 26471-62-5) Health Effects Notebook for Hazardous Air Pollutants. 亞甲基二苯基二異氰酸酯（英語： Methylene diphenyl diisocyanate ），通常縮寫為MDI，是一種芳族二異氰酸酯。 三種異構體是常見的，隨著環周圍的異氰酸酯基團的位置而變化：2,2'-MDI，2,4'-MDI和4,4'-MDI。4,4'異構體是應用最廣泛的，也被稱為4,4'-二苯基甲烷二異氰酸酯 [3] 。 這種異構體也被稱為純MDI。 The primary purpose of this chapter is to provide public health officials, physicians, toxicologists, and other interested individuals and groups with an overall perspective on the toxicology of TDI and MDI. (SDS) Certificates (COA/COO) Quality & Regulatory Calculators & Apps Webinars. 4,4'-Diphenylmethane diisocyanate may be toxic by ingestion, inhalation, or skin absorption. It has a CASRN of 9016-87-9. NIOSH: Pocket Guide to Chemical Hazards Material Type Value Methylene di-p-phenylene Ceiling 0. Its A comprehensive evaluation of the data on occupational exposure to the most important diisocyanates at workplaces was made and is reported here. RUO – Methylene diphenyl diisocyanate (MDI) is a white, odorless diisocyanate that may also occur in crystalline form. When melted, it becomes a clear liquid, no mechanical impurities. 5-10 26447-40-5 SECTION 4 – FIRST AID INHALATION For overexposure, remove to fresh air and seek medical attention. In certain niche applications, aliphatic isocyanates, such as isophorone diisocyanate (IPDI SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: February 27, 2015 Page 1 of 13 Section 1: IDENTIFICATION Product Name: Tytan Professional Subfloor High Yield Adhesive Pro Polymeric Methylene Diphenyl Diisocyanate (PMDI) 多亚甲基多苯基多异氰酸酯 MSDS Polymethylene polyphenyl polyisocyanate. ISO 9001 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Isocyanate MDI-I “A” Component Product Name: Company: Specialty Products, Inc. It exists in three isomers, 2,2'-MDI, 2,4'-MDI, and 4,4'-MDI. 32 841. There are no data available for PMDI. Suitable for use in polyurethane adhesives, elastomers, encapsulating agents. MDI-induced contact dermatitis has been reported. A flammable liquid. Endate 200 is also suitable for use in polyurethane paints, adhesives, sealants, structural foams, microcellular Diagnosis of diisocyanate asthma 203 Appendices (David I. com. 3 Possibility of hazardous reactions. Identification Product Name Tolylene 2,6-diisocyanate Cat No. This field is for validation purposes and should be left unchanged. MSDS Name: Methylenedi-p-phenyl diisocyanate Catalog Numbers: AC414280000, AC414281000, AC414285000 Synonyms: Diphenylmethane-4,4'-diisocyanate; MDI; 1,1'-Methylenebis[4-isocyanatobenzene]; 4,4'-Methylenediphenyl diisocyanate; Methylene bisphenyl isocyanate. Also consult the applicable MSDS sheet. Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. 05 mg/m3 0. 1 Product Material Safety Data Sheet or SDS for 4,4'-Diphenylmethane diisocyanate 101-68-8 from chemicalbook for download or viewing in the browser. 1 Tosyl chloride 98-59-9 202-684-8 < 0. 95(5 Pt. Products include monomeric and polymeric methylene diphenyl isocyanate (MDI), toluene diisocyanate (TDI), modified MDI, and MDI prepolymers. Chemical structures are included in Methylene diphenyl diisocyanate C&L Inventory Methylenediphenyl 4,4'-Diisocyanate Art. 2 mg/m3 Diisocyanate (CAS 101-68-8) 0. Hazard minimization Industrial science attempts to minimize the hazards of isocyanates through multiple SDS Number: 4707501 SAP Number: No Information Revision Date: 3/20/2024 Safety Data Sheet 24 Hour Emergency Phone Numbers 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 10-30 GHS07-GHS08 H315-317-332-334-335-351-373 Propylene glycols 25322-69-4 7-13 No Information No Information Tris(2-chloro-1-methylethyl) phosphate 13674-84-5 5-10 SDS Number: 4706101 SAP Number: Revision Date: 9/2/2022 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 7-13 GHS07 H332 Dimethyl ether 115-10-6 5-10 No Information No Information Tris(2-chloro-1-methylethyl) phosphate 13674-84-5 5-10 GHS07 H302-332 Methylene Diphenyl Diisocyanate (MMDI), Polymeric Methylene Diphenyl Diisocyanate (PMDI) and Toluene Diisocyanate (TDI). 0%(GC)(T) View Full Details The pure material methylene diphenyl-isocyanate is a solid that melts around 37°C. Providing a Safety Data Sheet (SDS) for the MDI product along with the drum helps ensure the re-conditioner will have information on the Methylene diphenyl diisocyanate is commonly referred to as MDI. , 2003). Environmental Protection Agency (EPA). : 584-84-9 نام شیمیایی: متیلن دی فنیل ایزوسیانات: مترادف ها (en) MDI ؛ Methylene bis(4-phenyl isocyanate) فرمول مولکولی Methylene Diphenyl Ceiling 0. 4 million tonnes, (SDS) for specific isocyanates. Like other isocyanates, MDI possesses the potential to sensitize the immune system, and is a well-recognized cause of occupational WANNATE® PM-700 is a polymeric methylene diphenyl diisocyanate (MDI) with higher functionality. 005 ppm methylenediphenyl (CAS 26447-40-5) Methylene diphenyl TWA 0. Methylene diphenyl diisocyanate (MDI) and toluene diisocyanate (TDI) are large-volume industrial chemicals used in the polyurethane industry for the production of flexible foam (mattresses, upholstered furniture), rigid foam for insulation (panels, refrigerators), integral skin foam (steering wheels, saddles), coatings, adhesives, sealants, and elastomers. Products; Applications & Protocols Life Science Research Solutions, Products, and Resources Synonyms: 4,4'-Diphenylmethane Diisocyanate, Methylene di-p-phenyl diisocyanate, Diphenylmethane 4,4'-diisocyanate, Bis(4-isocyanatophenyl)methane, MDI, 4,4'-Methylenebis(phenyl SAFETY DATA SHEET Version 6. SDS; Specifications; Other; Please Specify * Message * Email. 4,4'-Diphenylmethane diisocyanate. : Call your local poison 4,4’-Methylene diphenyl diisocyanate (MDI) 0. 20–23 Hydrolyzed/derivatized diisocyanate can be quantitated by gas chromatography (GC) coupled to mass spectrometry (MS), e. Specifications . NIOSH: Pocket Guide to Chemical Hazards Components Type Value Methylene Diphenyl Ceiling 0. The primary adverse health effects of this product are related to the Polymeric Isocyanate (MDI) component. 3. Do not empty into drains. o-(p-isocyanatobenzyl) phenyl isocyanate. All Photos (3) 4,4′-Methylenebis(phenyl isocyanate) Synonym(s): 4,4′-MDI, Bis(4-isocyanatophenyl)methane. 6 Revision Date 09/07/2024 Print Date 09/08/2024 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1. Environmental Protection Agency. Search. 5 %µµµµ 1 0 obj > endobj 2 0 obj > endobj 3 0 obj >/ExtGState >/XObject >/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 595. Endate 200 is a 2. Top Most Selling MDI Foam Making Chemical Methylene Diphenyl Diisocyanate from Leading South Korea Origin. Aromatic Isocyanate Wannate® CDMDI-100L SDS. Only SAFETY DATA SHEET THE DOW CHEMICAL COMPANY Product name: MOR-FREE™ L75-197 Issue Date: 08/30/2021 Print Date: 06/14/2022 THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. Primarily used in the production of polyurethane rigid insulation foam and polyisocyanurate foams. : 615-005-00-9 CAS-No. Please select Language. no data available. It exists in three isomers, (2,2′-MDI,2,4′-MDI, and 4,4′-MDI), however, the primary technical/commercial form of MDI is actually polymeric MDI, which is a mixture that contains 25–80% monomeric 4,4′-MDI as well as oligomers US EPA Integrated Risk Information System: Methylene Diphenyl Diisocyanate (monomeric MDI) and polymeric MDI (PMDI) (CASRN 101-68-8, 9016-87-9). 10. MDI is reacted with a polyol in the manufacture of polyurethane. Diisocyanates are (PPE) for working with methylene diphenyl diisocyanate (MDI) and to analyze the performance characteristics of several gloves, coveralls, splash suits, and other protective garments commonly used when working with MDI. Designed to be a replacement for pure 4,4-MDI that is liquid at room temperature. 5% NCO Please click here to request a sample, quotation or additional Basis for original (SCP) IDLH: The chosen IDLH is based on an analogy with toluene diisocyanate, which has an IDLH of 10 ppm. 6(5) - SDS and Declaration, Cosmetic Products Regulation, Annex II - Prohibited Substances, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, End-of-Life Vehicles Directive - Hazardous Substances, Active Implantable Medical Devices Directive The production , Applications and Toxicokinetics of 4,4'-Diphenylmethane diisocyanate; Methylene diphenyl diisocyanate?(MDI) is an important industrial product, We describe its chemical synthesis, application and . Products Genes Papers Technical Documents Site Content Chromatograms. U. It exists in three isomers, (2,20-MDI,2,40-MDI, and 4,40-MDI), however, the primary technical/commercial form of MDI is actually polymeric MDI, which is a mixture that contains 25–80% monomeric 4,40-MDI as well as oligomers MATERIAL SAFETY DATA SHEET Page: 1 of 11 Methylene-diphenyl-diisocyanate (MDI) 4 - 6 101-68-8 OSHA HAZARDOUS COMPONENTS (29 CFR 1910. Wannate 8219 is recommended for use as a binder in the carpet and foundry industries. 메틸렌 디페닐 디이소시아네이트는 크게 MDI 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는 2,2’-MDI, SAFETY DATA SHEET 1. It contains aromatic isocyanates that can cause skin, eye, and respiratory Material Safety Data Sheet or SDS for 4,4'-Diphenylmethane diisocyanate 101-68-8 from chemicalbook for download or viewing in the browser 1 The ingredient is the polymerized (cured) form of methylene-diphenyl-diisocyanate (MDI) resin in the raw composite panels used by Columbia for the production of PureBond assemblies. EMERGENCY OVERVIEW 3. It also includes Diphenylmethane 4,4'-diisocyanate (mixture of di-and triisocyanates) for synthesis. An aromatic diisocyanate is methylene diphenyl diisocyanate (MDI). We expect you to follow the SDS Number: 4700901 SAP Number: Revision Date: 9/2/2022 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 7-13 GHS07 H332 Propylene glycols 25322-69-4 5-10 No Information No Information Tris(2-chloro-1-methylethyl) phosphate 13674-84-5 5-10 GHS07 H302-332 SDS Number: 4701301 SAP Number: Revision Date: 9/2/2022 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 10-30 GHS07 H332 Propylene glycols 25322-69-4 7-13 No Information No Information Tris(2-chloro-1-methylethyl) phosphate 13674-84-5 7-13 GHS07 H302-332 SDS Number: 4701501 SAP Number: Revision Date: 9/2/2022 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 10-30 GHS07 H332 Propylene glycols 25322-69-4 7-13 No Information No Information Tris(2-chloro-1-methylethyl) phosphate 13674-84-5 7-13 GHS07 H302-332 ACGIH: Documentation of the Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) - Methylene Bisphenyl Isocyanate. 0 - < 65. : 101-81-5 1. Methylene Diphenyl Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: In U. 1 (Poison) ----- HAZARD SUMMARY * Methylene Bisphenyl Isocyanate can affect you when breathed in. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Components Type Value Diisocyanate TWA 0. This reaction forms a mixture of 4,4′ Manufacturer of Methylene Diphenyl Diisocyanate - Polymeric MDI, Wannate 8018(MDI) offered by Elavin Chemtech Private Limited, Ahmedabad, Gujarat. mdiの鉄道輸送用にjr貨物より承認登録された、日本陸運産業所有、日本ポリウレタン工業借受の鉄道私有コンテナ、ut8c-5026。 岡山県／旧、西岡山駅にて、2003年 4月17日撮影。. Methylene diphenyl diisocyanate (MDI) in commercial form typically exists as a mixture of 4,4'-MDI (monomer) and certain oligomers of MDI (Encyclopedia of Chemical Technology, 1983). 26 g/mol Hill Formula: C₁₅H₁₀N₂O Mitsui Chemicals, Inc. It is a water white liquid at room temperature and is manufactured in relatively small quantities. SECTION 13: Disposal Safety Data Sheet PureBond® Assemblies with pMDI Composite Core/Crossbands 1 The ingredient is the polymerized (cured) form of methylene-diphenyl-diisocyanate (MDI) resin in the raw composite panels used by Columbia for the production of PureBond assemblies. It exists in three isomers, (2,20-MDI,2,40-MDI, and 4,40-MDI), however, the primary technical/commercial form of MDI is actually polymeric MDI, which is a mixture that contains 25 Download the complete Methylene Diphenyl Diisocyanate (MDI) Action Plan (PDF) Access the public comment docket for the Methylene Diphenyl Diisocyanate (MDI) Action Plan (Docket ID EPA-HQ-OPPT-2011-0182) on Regulations. One urinary biomarker of diisocyanate exposure has been described in the literature to date, based on levels of a hydrolyzable diisocyanate derivative. Methylene diphenyl 101-68-8 >1 diisocyanate O-(p-isocyanatobenzyl)phenyl 5873-54-1 Diphenylmethane 4,4' -diisocyanate; Diphenylmethane diisocyanate; Diphenylmethane-4,4' -diisocyanate; HSDB 2630; Hylene m50; Isocyanic acid < methylenedi-p-phenylene ester; Isonate 125 mf; Isonate 125m; MDI; Methylene Diphenyl Diisocyanate (monomeric MDI) and polymeri MDI (PMDI) Methylene di (phenylene isocyanate) Lupranat® isocyanates from BASF are utilized across a large range of applications and industries. General Information : Call a POISON CENTER or doctor/physician if you feel unwell. OSHA Table Z-2 (29 CFR 1910. 33. J. ] Short-term exposure guidelines: None developed. Now we are expanding our Desmodur® CQ portfolio by offering you a climate neutral MDI (methylene diphenyl diisocyanate), thanks to the use of alternative raw materials, based on plant waste. 14 Revision Date 09/08/2024 Print Date 09/09/2024 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1. The PCBU must also obtain a copy of the Safety Data Sheet and make it readily accessible to workers involved in using SAFETY DATA SHEET Version 6. SAFETY DATA SHEET RugbyÒ 200 CS SDS Methylene diphenyl diisocyanate (polymeric) 9016-87-9 5-10 Naphtha (petroleum), heavy aromatic 64742-94-5 1-5 Danger Hazard Statements H302 - Harmful if swallowed H332 - Harmful if inhaled H370 - Causes damage to organs H372 - Causes damage to organs through prolonged or repeated exposure WANNATE® MDI-50 is a 50/50 blend of 4,4'-MDI (methylene diphenyl diisocyanate) and 2,4-MDI. 4 European Union’s Annex VI to Regulation (EC) No 1272/2008, updated by the 1st Adaption to Technical Progress to the Regulation. 005 ppm TWA Methylene bisphenyl isocyanate (MDI) N. CAS No. 1 Product identifiers Product name : Diphenylmethane 4,4'-diisocyanate (mixture of di-and triisocyanates) for synthesis Product Number : 8. In case of unconsciousness place patient stably in side position for We are consistently pursuing our path to a circular economy and more sustainability. Therefore, MSDS Name: Methylenedi-p-phenyl diisocyanate Catalog Numbers: AC414280000, AC414281000, AC414285000 Synonyms: Diphenylmethane-4,4'-diisocyanate; MDI; 1,1' Material name: Methylene di-p-phenylene diisocyanate 13916 Version #: 01 Issue date: 01-28-2015 SDS US This material safety data sheet (MSDS) provides information on the hazards, composition, first-aid, fire-fighting and accidental release measures of ISOCYANATE A-2732, a polymeric DESMODUR VK 5 is a raw material for coatings, adhesives, sealants, or elastomers in industrial applications. 4,4’-MDI can be obtained by purifying the diphenylmethane diisocyanate mixture. 101-68-8 and 9016-87-9) in Support of Summary Information on the Integrated Risk Information System (IRIS). NIOSH: Pocket Guide to Chemical Hazards Components Type Value Heptane (CAS 142-82-5) Ceiling 1800 mg/m3 440 ppm TWA 350 mg/m3 85 ppm Methylene Diphenyl Ceiling 0. provided in the pMDI supplier’s Safety Data Sheet (SDS) and other technical guidance that may be available at www. 02 ppm SDS Number: 1009001 SAP Number: Revision Date: 9/2/2022 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 7-13 GHS07 H332 Propanol, [(1-methyl-1,2-ethanediyl)bis(oxy)]bis-, polymer with 1,1'-methylenebis[isocyanatobenzene] Shop Methylene di-p-phenyl diisocyanate, 98%, flakes, 4,4'-methylenebis phenyl isocyanate, methylbisphenyl isocyanate, 1,1'-methylenebis 4-isocyanatobenzene, methylene diphenyl diisocyanate: PubChem CID: 7570: ChEBI: SDS. Also suitable for use in polyurethane paints, adhesives, sealants, structural foams, microcellular integral skin foams, automo Diisocyanate TWA 0. Methylene Diphenyl TWA 0. 1000) Components Type Value Toluene (CAS 108-88-3) Ceiling 300 ppm TWA 200 ppm US. This product consists primarily of high molecular weight polymers which are not expected to be hazardous. HAZARDS INDENTIFICATION 3. Hexamethylene Diisocyanate. 13 Revision Date 01/02/2025 Print Date 01/03/2025 SECTION 1. 5–7 Major uses for MDI are in the production of polyurethane-based products and as a binding agent for various industrial processes. environmental laws and in accordance with the manufacturer’s Safety Data Sheet (SDS). Diphenylmethane 4,4'-diisocyanate MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. 588. Details of the 4,4'-methylenediphenyl diisocyanate EC Number: 202-966-0 EC Name: 4,4'-methylenediphenyl diisocyanate CAS Number: 101-68-8 Molecular formula: C15H10N2O2 isocyanaic acid, methylene di-p-phenyleneester(6CI,8CI) methylene-di-p-phenylene diisocyanate methylenebis(p-phenylene isocyanate) p,p'-Diphenylmethane diisocyanate 4,4’-methylene diphenyl diisocyanate. SDS; CoA; Synonyms: Methylenediphenylene diisocyanate CAS #: 101-68-8 EC Number: 202-966-0 Molar Mass: 250. Polymeric Methylene Diphenyl Diisocyanate; PMDI; PU polyurethane prepolymer MDI; Polymethylene polyphenyl polyisocyanate ISO 9001：2015 REACH; HUNTSMAN RUBINATE® M is a polymeric MDI (methylene diphenyl diisocyanate). polyurethane. E. ACGIH Threshold Limit Values Components Type Value Methylene Diphenyl TWA 0. Monomeric MDI is a white to yellowish solid at room temperature with no odor. Catalog Number 820797 Product Name Diphenylmethane 4,4'-diisocyanate SDS; Certificates; Chemical Structure Knowledgebase & FAQs; Advanced. There are three common isomers: 2,2′-MDI, 2,4′-MDI, and 4,4′-MDI. 2. C of A & Other Certificates Methylenediphenyl 4,4'-Diisocyanate (Granulated) Product # M3310: CAS RN: 101-68-8: Purity / Analysis Method: >97. The most common isomer, commonly known as 4,4′-diphenylmethane diisocyanate, is the 4,4′ isomer. Handling Precautions. Allergy Clin. Other adverse effects. Fill out the form below and we will be in touch shortly. Inhalation: Move to an area free from further exposure. Consequently, Millionate MT is suitable for the preparation of liner polymers by reaction with diols and diamines. Primarily used in the production of polyurethane elastomers and prepolymers for polyurethane This Public Health Statement summarizes the Agency for Toxic Substances and Disease Registry’s (ATSDR) findings on toluene diisocyanate (TDI) and methylenediphenyl diisocyanate (MDI), including chemical characteristics, exposure risks, possible health effects from exposure, and ways to limit exposure. Polyurethane from methylene diphenyl diisocyanate and 1,6-hexanediol. * Methylene Bisphenyl Isocyanate can irritate the skin causing a rash or burning feeling on contact. Wannate 8219 is supplied at 40-70 cps at 25C as a brown SAFETY DATA SHEET 1. US EN. For more information search the European Chemicals Agency database. Get medical HUNTSMAN RUBINATE® 9225 is a carbodiimide modified 4,4-MDI (methylene diphenyl diisocyanate) that also contains some 24-MDI. Disposal of Waste MDI. WANNATE® MDI-100 can be widely used in the production of various polyurethane elastomers including cellular elastomers, thermoplastic elastomers, cast elastomers, synthetic leather, adhesives, Methylene diphenyl diisocyanate (MDI); Oligomeric MDI (4,4’-Methylenediphenyl diisocyanate, oligomers) CAS # 101-68-8; 25686-28-6. INTRODUCTION. Pursuant to 49 CFR 171. 02 ppm US. Bernstein) 203 Reading217 4 The environment 229 R E Bailey, A Gard, K H den Haan, F Heimbach, D Pemberton, H Tadokoro, M Takatsuki and Y Yakabe A general approach to environmental risk assessment 229 Exposure 233 Sources of exposure 233 Distribution and persistence 237 Biodegradation 256 SAFETY DATA SHEET Revision Date 24-Dec-2021 Revision Number 6 1. This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications. : Hypersensitivity pneumonitis (extrinsic allergic alveolitis) induced by isocyanates. If in a solution 4,4'-Diphenylmethane diisocyanate may or may not burn depending on the nature of the material and/or the solvent. Supplied as a solid. Our team of experts are at the ready. 2 Relevant identified uses of the substance or mixture and uses Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: In U. Wannate MDI-50 is primarily used in the production of polyurethane elastomers and for polyurethane coatings, adhesives, and foams. 005 ppm Naphtha 2,4′-Methylenebis(phenyl isocyanate) 97%; CAS Number: 5873-54-1; EC Number: 227-534-9; Linear Formula: CH2(C6H4NCO)2 at Sigma-Aldrich Showing 1-9 of 9 results for "methylene diphenyl diisocyanate" within Products. 1. 安全性情報 Methylene diphenyl diisocyanate (MDI) is a white, odorless diisocyanate that may also occur in crystalline form. SECTION 13: Disposal considerations. 8, “transloading” means “the transfer of a hazardous material by any person from one bulk packaging to an-other bulk packaging, from a bulk packeging to a non-bulk packaging, or from a 메틸렌 디페닐 디이소시아네이트(영어: methylene diphenyl diisocyanate, MDI)는 방향족 디이소시아네이트류 화학 물질이다. 1 Product identifiers Product name : Diphenylmethane Product Number : D209317 Brand : Aldrich CAS-No. Immunol. Methylene diphenyl diisocyanate (MDI) is the most abundantly produced and consumed diisocyanate, with applications in the production of truck-bed liners and spray foam insulation, among other uses (Allport et al. SAFETY DATA SHEET Version 6. Different methods can synthesize Diphenylmethane-4,4’-diisocyanate (MDI). I will try to be as specific as possible from the Invisalign MSDS (material GHS - SDS; UN Class - UN Number - UN Guide 4,4'-Methylenediphenyl diisocyanate; Methylene diphenyl diisocyanate (monomeric and pol; 1,1-methylenebis(4-isocyanatobenzene) methylenebis(4-isocyanatobenzene) Methylenedi-p-phenyl diisocyanate; Methylenedi-p-phenyl diisocyanate, stabilized flakes, contains 1. ChemicalBook. (Tokyo: 4183; President & CEO: HASHIMOTO Osamu) announced that affiliate Kumho Mitsui Chemicals Inc. (SPI) 2410 – 104th St Ct S, Ste D Lakewood, WA 98499 Phone: 253. For the DII, methylenediphenyl diisocyanate (MDI—also called diphenylmethane diisocyanate) and toluene diisocyanate (TDI) are the most widely used PU raw materials. 2 Relevant identified uses of the substance or mixture and uses advised against 4,4'-Diphenylmethane diisocyanate, MDI, Methylene di-p-phenylene ester of isocyanic acid, Methylene bis(4-phenyl isocyanate) White to light-yellow, odorless flakes. pure 4,4'-methylene diphenyl diisocyanate. See annual publication for most recent information. g. 2 mg/m3 diisocyanate (CAS 101-68-8) 0. Encyclopedia. Isocyanates and thioisocyanates, such as DIPHENYLMETHANE-4,4'-DIISOCYANATE, are incompatible with many classes of compounds, reacting exothermically Volume-wise, hexamethylene diisocyanate (HDI) and isophorone diisocyanate (IPDI) are the most commercially important representatives of ADI. Identification Product identifier DUNAPOL™ AD 3140 Other means of identification SDS number Version 1 Product code 202009 Methylene diphenyl diisocyanate 101-68-8 10-20 O-(p-isocyanatobenzyl)phenyl Isocyanate 5873-54-1 5-10 Polymethylene polyphenyl isocyanate 9016-87-9 5-10 Hydrogenated MDI (H 12 MDI or 4,4′-diisocyanato dicyclohexylmethane) is an organic compound in the class known as isocyanates. Wannate 8219 has low viscosity and good flowability. Methylene Diphenyl Diisocyanate (MDI) About Methylene Diphenyl Diisocyanate (MDI) Enquire Now. Toxicological Review of Methylene Diphenyl Diisocyanate (MDI) (CAS No. BASF Corp. Stable under recommended storage conditions. The content of monomeric MDI generally is between 45% and 65% on a w/w basis (Mobay, 1983). In animal studies, a skin-sensitizing effect (type IV) has been found for MDI but not for PMDI. (Seoul, South Korea; CEO: PARK Chan-Koo) has commenced operations late September at additional production facilities for methylene diphenyl diisocyanate (MDI). Stability and reactivity 10. 1 Product identifiers Product name : 4,4′-MDI Product Number : 33428 Brand : Sigma-Aldrich Index-No. 1 Reactivity. The requested SDS is not available. The term polyurethane applies to a large number of polymers formed through the polyaddition of The current safety data sheet (SDS) should be used in conjunction with this publication because the SDS is updated as changes in Material Safety Data Sheet or SDS for Diphenylmethane 4,4'-diisocyanate 820797 from Merck for download or viewing in the browser. Risk factors. : AC208040000; AC208040010; AC208040050 CAS No 91-08-7 Synonyms 2-Methyl-1,3-phenylene diisocyanate Recommended Use Laboratory chemicals. Title: MSDS for Invisalign Appliance Materials – Millionate® MR/MT : Millionate MT [Monomeric MDI] Millionate MT is an aromatic diisocyanate having two isocyanate groups of equal reactivity. (1967) Material Safety Data Sheet for diethylamine and an evaluation of the acute toxicity and irritantcy potential of 4 polyurethane intermediates with cover letter dated 042689, The Hine Labs Inc. Methylene diphenyl 4,4'-diisocyanate (MDI); numbering of the ring atoms shown with blue numbers Isophorone diisocyanate. Safety Data Sheet (SDS) EN: Wannate® CDMDI-100L TDS. 05 mg/m3 methylenediphenyl (CAS 26447-40-5) 0. National Center for Environmental Assessment, Office of Research and Development, Research Triangle Park, NC. This document provides information on the identification, hazards, composition, and disposal of methylene diphenyl diisocyanate (MDI), a laboratory chemical. 005 ppm Diisocyanate (CAS 101-68-8) Toluene (CAS 108-88-3) TWA 20 ppm US. SDS Pricing; 33428: analytical standard: Expand. Search Products: ChemicalBook >> CAS DataBase List >>Methylene Diphenyl Diisocyanate. Diphenylmethane diisocyanate, isomers and homologues 25-50 9016-87-9 4,4'-methylene diphenyl diisocyanate 25-50 101-68-8 Methylene diphenyl diisocyanate 2. EMERGENCY OVERVIEW Material Safety Data Sheet Align Technology, Inc. Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: In U. 7-functional polymeric MDI (methylene diphenyl diisocyanate), Endate 200 is primarily used in the production of polyurethane rigid insulation foam and polyisocyanurate foams. 6 μg/m3 based on an annual averaging time. The slightly higher functionality and intermediate viscosity of Wannate PM-700 Isocyanates come in different chemical forms, the most commonly used are methylene diphenyl diisocyanate (MDI), toluene diisocyanate (TDI), and hexamethylene diisocyanate (HDI); TDI is more hazardous because it is more volatile and the vapour can be breathed in. 2 Relevant identified uses of the substance or mixture and uses MATERIAL SAFETY DATA SHEET Isocyanate MDI-I “A” Component Revised Date: 08/11/09 Page 1 of 7 Specialty Products, Inc. [1] More specifically, it is an aliphatic diisocyanate. Many variations of MDI are commercially available, and these variations fall into three major classes: monomeric MDI, ‘modified’ MDI's, and polymeric MDI's. Methylene diphenyl diisocyanate, most often abbreviated as MDI, is an aromatic diisocyanate. 7% NCO. TDI is used to make flexible polyurethane foam for furniture, bedding, carpet underlay and Methylene Diphenyl TWA 0. methylene diphenyl diisocyanate 905-806-4 < 10 Hexamethylene diisocyanate polymer 28182-81-2 500-060-2 1 - 5 hexamethylene-di-isocyanate 822-06-0 212-485-8 < 0. Please refer to the Safety Data Sheet (SDS). 05 Common Name: METHYLENE BISPHENYL ISOCYANATE CAS Number: 101-68-8 DOT Number: UN 2489 DOT Hazard Class: 6. It contains descriptions and evaluations of toxicological studies and epidemiological investigations and provides conclusions, where possible, on the relevance of toxicity and 4,4'-Methylene diphenyl diisocyanate; 2,2'-Methylene diphenyl diisocyanate; o-(p-Isocyanatobenzyl) phenyl isocyanate; Methylene diphenyl diisocyanate (MDI) including materials, containers and pipework (cl. EPA/OTS Doc #: 86-890000191. Wannate PM-700 was specifically designed for use in the production of both PUR and PIR (continuous and discontinuous) block foams. Uses advised against Food, drug, pesticide or biocidal product use. CAS 101-68-8, molar mass 250. . 02 ppm TWA 0. 25 g/mol. : 101-68-8 1. GC-MS. Technical Data Sheet (TDS) EN: Digital Media. 20–22, 24,25 Urine levels of hydrolyzable diisocyanate The most widely used aromatic diisocyanates are toluene diisocyanate (TDI) and methylene diphenyl diisocyanate (MDI). It is a white to light yellow- green crystal at room temperatures. Assessing and Managing Chemicals under TSCA How EPA Evaluates the Safety of Existing Chemicals متیلن دی فنیل دی ایزوسیانات (MDI) ( Methylene Diphenyl Di-Isocyanate ) خواص و کاربردها متیلــن دی فنیل دی ایزوســیانات که بانام اختصاری MDI شــناخته می شــود ترکیبی آروماتیــک از خانواده دی ایزوســیاناتها است. CAS# 137873-51-9 2. 3 % 108-90-7) 1000 ppm US. Product. 005 ppm Naphtha functional. Skip to Content. : 615-006-00-4 CAS-No. 3% of the global market in the year 2000. 1 Product identifiers Product name : Toluene 2,4-diisocyanate Product Number : 89870 Brand : Sigma Index-No. It is widely used ion the production of microcellular elastomers, thermoplastic elastomers, cast elastomers, synthetic leathers, and CASE (Coatings, Adhesives, Sealants and Elastomer) applications. 2,2’-methylene diphenyl diisocyanate. Manage Digital Media and SDS; Certificates; Chemical Structure Knowledgebase & FAQs; Advanced. 1 Safety Data Sheet (SDS) Language. 4,4'-Methylene diphenyl isocyanate is produced in two grades of purity (Schauerte 1983): . 7101 Waste methylene diphenyl diisocyanate (MDI) handling is required to be in compliance with U. The addition of the 2,4'-MDI enhances the performance and properties of the resulting polyurethane system. 2 Chemical stability. : 599-67-7 1. After inhalation exposure, MDI reacts with Methylene diphenyl diisocyanate (MDI) is now the most abundantly produced and utilized diisocyanate world-wide. gov. 1998. V. Investigations have been undertaken with MDI and TDI Polymeric diphenylmethane diisocyanate 9016-87-9 45-70 GHS07 H332 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 10-30 GHS07 H332 1,1,1,2-Tetrafluoroethane (HFC-134A) 811-97-2 10-30 GHS07 H336 1,2-trans-Dichloroethylene 156-60-5 1-5 GHS07 H302 The text for GHS Hazard Statements shown above (if any) is given in the "Other information Find Methylene Diphenyl Diisocyanate and related products for scientific research at MilliporeSigma. Each item on this reference table is more fully described in safety data sheet (SDS) for materials to avoid or contact the supplier with additional questions. Please Contact Us for more information. S. 92] /Contents documentation “4,4′-Methylene diphenyl diisocyanate (MDI) and “polymeric” MDI (PMDI)” 1997). There is no detectable MDI monomer (CAS# 101-68-8) in the Polyurethanes (PU) are polymers made with diisocyanates such as MDI (4,4'-methylene diphenyl diisocyanate) and TDI (2,4-toluene diisocyanate and 2,6-toluene diisocyanate). Methylene Diphenyl IDLH 75 mg/m3 Diisocyanate (CAS 101-68-8) Impurities Type Value Chlorobenzene (CAS IDLH 1. Product Family. 物理性質. Wannate MDI-50 provides better flowability for the production of injection molding. IDENTIFICATION 1. 20797 Catalogue No. 10 Revision Date 03/02/2024 Print Date 07/13/2024 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1. 005 ppm Methylene diphenyl TWA 0. 005 ppm diisocyanate (CAS 101-68-8) Canada. In case of unconsciousness place patient stably in side position for ChemSpider record containing structure, synonyms, properties, vendors and database links for 4,4′-Methylenediphenylene diisocyanate, 101-68-8, Methylene diphenyl diisocyanate WANNATE® MDI-100 is pure MDI. 8–10 MDI is generally considered safer than other commonly used diisocyanates because its low This Action Plan addresses the use of methylene diphenyl diisocyanate (MDI) and related compounds (See Appendix 1) in products that may result in consumer and general population exposures, particularly in or around buildings, including homes and schools. Additives 3. ジフェニルメタンジイソシアネートは、通常mdiと略され、芳香族 ジイソシアネートの1つである。mdiには、2,2'-mdi, 2,4'-mdi Polyurethane from methylene diphenyl diisocyanate and 1, 6-hexanediol. 7-32. Hide. • Elevated airborne concentrations may cause irritation of the eyes; therefore, MSDS File: SDS. Also find Methylene Diphenyl Diisocyanate price list | ID: 25561282012 Please refer to the Safety Data Sheet (SDS Diphenylmethane diisocyanate, isomers and homologues 25-50 9016-87-9 4,4'-methylene diphenyl diisocyanate 25-50 101-68-8 Methylene diphenyl diisocyanate 2. The 4,4' isomer is most practically useful, and is also known as Pure MDI. Filter & Sort. ghq zlbs ogue aowm qnycom njwyi trjra pepn ucjvo dyesek